Abstract:
The anomalous distribution of the gases in headspace of shallow sediments could be applied as an indicator to explore whether there are gas hydrate accumulations underneath. Comprehensive analyses of hydrocarbon gas composition and isotopic composition of methane in headspace gas in shallow sediments and related drilling cores in the Shenhu area are studied in this paper. Results show that CH
4 is the major component of gases from the total 291 samples 1 mbsf (bsf, below sea floor) with trace C
2H
6 and C
3H
8, and the normalized concentrations of CH
4 range from 2.49 to 77.23 μL/kg with an average value of 15.22 μL/kg. CH
4 concentration from 12 anomalies were determined using tendency analysis method, and they extend in a NE direction as a whole, that is obviously controlled by NE trend fractures. The δ
13C values of CH
4 from 14 headspace gas samples from Sites 4PC and 23PC range from -74.3‰ to -46.2‰ with an average value of -60.9‰(PDB), and the ratios of C
1/(C
2+C
3) range from 5.78 to 49.45 with an average of 16.23. This indicates that hydrocarbon gases of those samples are mainly microbial gas with small fraction of thermogenic gas. Isotopic anaylses were applied to 4 headspace gas samples collected from the drilling cores. It is found that δ
13C and δD values of CH
4 are -62.2‰ to -54.1‰ (PDB) and -225‰ to -180‰ (SMOW), respectively, and the ratios of C
1/(C
2+C
3) was ranging from 575 to 1 668, suggesting that CH
4 seems to be microbial gas or mixed gases with microbial gas dominating, and CH
4 was mainly generated from microbial CO
2 reduction and there is a little contribution from thermogenic gas. Our study indicates that the headspace hydrocarbon gases in shallow sediments were from gas hydrates, hydrocarbon source rocks or gas accumulations underneath. The hydrocarbon gases migrated upward along faults and diapir structures. Hydrocarbon gases originated from the dissociation of gas hydrates are mainly microbial gas, and those from hydrocarbon source rocks or gas accumulations are thermogenic gases in origin.