多元地球化学指标约束下全球铁锰结壳的成因分析与对比

    Genetic analysis and comparison of global ferromanganese crusts constrained by multiple geochemical indicators

    • 摘要: 铁锰结壳是分布于全球大洋海山、海岭等硬质基底上的海相铁锰氧化物沉积,兼具关键金属资源潜力和古海洋环境重建价值,但现有研究缺乏全球尺度跨洋盆的系统对比,对多元地球化学指标与环境因子耦合关系的解析仍显不足。本文汇编了全球不同海域超3 000个站位的铁锰结壳地球化学数据集,基于稀土元素、主微量元素等多元地球化学指标,结合成因判别与主成分分析(PCA),系统开展全球铁锰结壳的成因判别、跨洋盆对比及其环境驱动机制研究。结果表明,全球铁锰结壳分布受多尺度构造-环境耦合控制,优先富集于长期稳定的构造隆起区,主要发育于800~3 500 m水深区间。多元地球化学指标结果表明,北冰洋、大西洋、太平洋、印度洋铁锰结壳均以水成成因为主,局部受成岩改造或热液混入影响。PCA揭示不同海域结壳生长的环境驱动机制差异显著,北冰洋以水成型铁锰结壳为主,生长受控于强氧化环境与陆源碎屑输入,其中,陆源碎屑引发的弱成岩改造是区别于其他大洋的显著特征;大西洋结壳以水成成因为主,叠加磷酸盐化成岩作用;太平洋结壳以水成成因为主,同时整合陆源输入、表层生产力与热液活动信号,并在西太平洋海山区普遍遭受强烈磷酸盐化改造;印度洋结壳以水成成因为主体,但叠加了磷酸盐化成岩改造与西北澳大利亚陆源碎屑的稀释效应。本研究为全球尺度结壳成因类型判别及不同洋盆结壳成因分异规律与环境控制机制的厘清,提供了数据支撑与理论参考。

       

      Abstract: Ferromanganese crusts are marine Fe-Mn oxide deposits widely distributed on hard substrates such as seamounts and oceanic ridges throughout the global oceans. They represent both important potential resources of critical metals and valuable archives of pale-oceanographic reconstruction. However, global-wise comparative studies across different ocean basins remain limited, and relationships between multi-geochemical proxies and environmental factors are poorly understood. Therefore, we compiled and studied global geochemical datasets containing more than 3 000 ferromanganese crust samples from various oceanic regions. Based on multiple geochemical proxies, including rare earth elements, major elements, and trace elements, together with genetic discrimination diagrams and principal component analysis (PCA), we systematically investigated the genetic classification, inter-oceanic variations, and environmental controls of global ferromanganese crusts. Results indicate that the distribution of global ferromanganese crusts is governed by multi-scale tectonic-environmental coupling processes, with preferential accumulation in long-lived stable tectonic uplift regions, mainly at water depths of 800-3 500 m. Multi-geochemical proxy analyses showed that ferromanganese crusts from the Arctic, Atlantic, Pacific, and Indian Oceans are predominantly hydrogenetic in origin, with localized influences from diagenetic alteration and hydrothermal contributions. PCA results further revealed significant differences in environmental controls on crust growth among ocean basins. The Arctic ferromanganese crusts are mainly hydrogenetic characterized by growth under strongly oxic conditions with substantial terrigenous detrital inputs and unique weak diagenetic modification associated with terrestrial material input compared with other oceans. The Atlantic crusts are dominated by hydrogenetic processes with additional influence from phosphatization. The Pacific crusts are primarily hydrogenetic with simultaneously recorded signals from terrigenous input, surface productivity, and hydrothermal activity; and extensive phosphatization is widespread in seamount regions of the western Pacific. The Indian Ocean crusts are also predominantly hydrogenetic but have experienced additional phosphatization diagenesis and dilution effects caused by terrigenous detrital inputs from northwestern Australia. This study provided a comprehensive dataset support and theoretical framework for worldwide genetic classification of ferromanganese crusts, and shall improve our understanding of the spatial differentiation of crust formation processes and the environmental mechanisms controlling their evolution across different ocean basins.

       

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