湛江湾沉积物稀土元素特征及其地质意义

    Characteristics and Provenance Analysis of Rare Earth Elements in Sediments from Zhanjiang Bay

    • 摘要: 本文对湛江湾33个沉积物的稀土元素进行了系统对比分析,以揭示其组成特征、影响因素及主要物质来源与贡献机制。结果表明:湛江湾沉积物平均粒径为21.21 μm,以粉砂、砂质粉砂为主;稀土元素总量(ΣREE)为114.06~286.83 μg/g,平均含量为208.83 μg/g,呈轻稀土(LREE)富集、重稀土(HREE)均一、Eu负异常明显和Ce无明显异常等特点。结果分析表明,研究区总稀土含量受沉积物粒度、化学蚀变指数(CIA)及来源等明显制约。湛江湾稀土元素标准球粒陨石配分模式与广东沿海花岗岩、中国陆壳等物质具有明显相似特征,表现出较强的亲陆源性。利用球粒陨石标准化计算的(Gd/Yb)N-(La/Yb)N和δEu-(La/Yb)N指标进行物源判别,结果显示湛江湾沉积物主要来源于花岗岩(或花岗质陆壳)、环湛江湾玄武岩及第四纪沉积物的混合来源,且初步发现湛江湾沉积物稀土元素富集的物源贡献比例可能正逐渐发生变化。

       

      Abstract: A systematic comparative analysis of rare earth elements (REEs) in 33 sediment samples from Zhanjiang Bay was conducted to reveal their distribution characteristics, influencing factors, primary material sources, and transport mechanisms. Results show that the average size of the sediment particles is 21.21 μm. Most of them are made up of silt and sandy silt. The total REE content (ΣREE) ranges from 114.06 to 286.83 μg/g, with an average of 208.83 μg/g. The sediments are characterized by light REEs (LREE) enrichment, and flat heavy REEs (HREE) pattern, a pronounced negative Eu anomaly, and an absence of significant cerium (Ce) anomaly. Correlation analysis between ΣREE with grain size, the Chemical Index of Alteration (CIA), and major mineral elements revealed that the REE distribution in this study area is closely related to the sediment grain size, CIA and the provenance. The chondrite-normalized REE patterns of Zhanjiang Bay sediments are similar to those of coastal granites in Guangdong and the upper continental crust of China, which demonstrate a strong terrigenous influence. Provenance discrimination by means of the δEu-(La/Yb)N and (Gd/Yb)N-(La/Yb)N diagrams which calculated from chondrite-normalized values, suggest that the sediments of Zhanjiang Bay are mainly derived from a mixture of granite or granitic continental crust, the surrounding basaltic rocks of Zhanjiang Bay, and the Quaternary sediments. Our preliminary finding also indicates that the relative contributions to REE enrichment in the sediments of Zhanjiang Bay are likely gradually changing.

       

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