日照港海洋沉积物重金属时空分布及风险评价

    Spatiotemporal distribution and risk assessment on heavy metals in marine sediments in Rizhao Port

    • 摘要: 海洋沉积物中重金属元素的含量和分布特征等是衡量海洋环境污染状况、追溯环境演化过程的关键指示性参数。本文基于2021—2024年采集的日照港岚山港区邻近海域表层沉积物样品,开展了6种重金属和有机碳(OC)等环境要素分析,探讨了研究区各元素的时空分布及地球化学特征。研究结果表明,研究区表层沉积物中铜(Cu)、铅(Pb)、镉(Cd)、铬(Cr)、锌(Zn)和汞(Hg)含量范围分别为10.4~27.9、10.5~26.3、0.0366~0.160、23.8~75.9、41.4~122和0.008500.0938 µg/g,含量总体处于典型港口海域水平。时间序列上,Cu、Pb、Cd和Zn含量虽存在年际波动,但整体趋于稳定;而Cr和Hg含量呈现出逐年递减趋势。受与港口运营和工业活动密切相关的混合人为活动影响,港区沉积物重金属在空间分布上整体呈现出港口近岸高值的特征,同时具有一定程度的年际变化差异。日照港岚山港区沉积物中Pb、Cr和Hg处于清洁水平,Cu与Zn为清洁至轻度污染,而Cd虽整体污染程度较轻,但在2024年出现局部偏中度污染;海域沉积环境整体处于重金属低—中生态风险水平。

       

      Abstract: The content and distribution characteristics of heavy metal elements in marine sediments are key indicative parameters for measuring the status of marine environmental pollution and tracing the process of environmental evolution. In this study, surface sediment samples were analyzed for six heavy metals and organic carbon (OC), which were collected from the adjacent sea area of Lanshan Port, Rizhao Port between 2021 and 2024, and the temporal and spatial distributions as well as geochemical characteristics of each element were discussed. The content ranges of six heavy metals (Cu, Pb, Cd, Cr, Zn, Hg) in the surface sediments of the study area were 10.4-27.9, 10.5-26.3, 0.0366-0.160, 23.8-75.9, 41.4-122, and (0.008 50-0.0938) µg/g, which were generally at the level typical of port marine areas . In the time series, although the contents of Cu, Pb, Cd, and Zn exhibited interannual fluctuations, they tended to be stable overall; the contents of Cr and Hg showed a decreasing trend year by year. Affected by mixed anthropogenic activities closely associated with port operations and industrial activities, the heavy metals in port-area sediments generally exhibit a spatial distribution characterized by high concentrations in the nearshore zones of the port, while also showing certain interannual variations. The levels of Pb, Cr and Hg in the sediments were at a clean level; Cu and Zn ranged from clean to slightly polluted; while Cd, although generally slightly polluted, showed locally moderate pollution in 2024; Overall, the marine sedimentary environment was at a low to moderate ecological risk level of heavy metals.

       

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