渤海曹妃甸海域表层沉积物常量元素特征及其对源区风化特征的指示意义

    Geochemical characteristics of major elements in surface sediments of Caofeidian offshore area in the Bohai Sea: implications for the weathering characteristics of the source area

    • 摘要: 通过对渤海曹妃甸海域的161个表层沉积物样品和环渤海湾主要河流的30个表层沉积物样品进行常量元素测试,研究常量元素组合特征及其影响因素,并运用化学蚀变指数(CIA),探讨沉积物风化特征及其物源指示意义。结果表明,曹妃甸附近海域表层沉积物常量元素氧化物组分以SiO2和Al2O3为主,Si、Al、Fe、K、Mg、P、Ti 7种元素“粒度效应”显著,受沉积物粒径影响,除Si外,其他6种元素在研究区基本呈现南高北低、西高东低的分布格局。元素Ca、Na受物源的影响显著,Mn的分布与氧化还原条件相关。风化程度研究表明,曹妃甸海域砂粒级和粉砂粒级沉积物CIA分别为48.4和57.2,CIA与沉积物粒径呈正相关性,与周边水系沉积物同处于初级风化阶段,其源岩成分接近二长花岗岩。地形和气候差异是影响滦河水系和海河水系沉积物风化程度差异不可忽视的重要因素。

       

      Abstract: Based on the analysis of major element characteristics of 161 surface sediment samples from the Caofeidian offshore area of the Bohai Sea and 30 surface sediment samples from major rivers around Bohai Bay, the assemblage characteristics and influencing factors of major elements were studied. Considering the characteristics of major elements in stream sediment along Bohai Bay, the weathering and provenance were discussed using the chemical index of alteration (CIA). Results show that SiO2 and Al2O3 constitute the predominant elements in the surface sediment of the study area. Seven elements, i.e., Si, Al, Fe, K, Mg, P, and Ti, clearly demonstrate a significant "grain size effect". Except for Si, the distribution patterns of other six elements follow a discernible trend consistently. Higher concentrations were observed in the southern and western regions, while lower concentrations prevail in the north and east. It is worth noting that CaO and Na2O exhibit a substantial influence from their provenance, while the distribution of MnO appears to be closely correlated with redox conditions. The CIA values of sand and silt-sand sediments in Caofeidian sea area are 48.4 and 57.2, respectively. This index is positively correlated with sediment particle size, and it is in the primary weathering stage with the surrounding stream sediments. Furthermore, the source rock composition of sediments in the Caofeidian offshore area bears striking similarities to that of adamellite. Topographic and climatic variations are important factors affecting the differences in the weathering intensity of sediments in the Luanhe River system and the Haihe River system.

       

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