南科1井的地球化学特征及其与陆源输入的关系

    Geochemical characteristics of the NK-1 core and their relationships with terrigenous input

    • 摘要: 生物礁作为一种重要的碳酸盐沉积类型,记录了地球表层演化历史的重要信息。目前,生物礁研究主要集中在古生态学、沉积学和礁体的微相分析等领域,而对于陆源输入等古环境方面的研究相对较少。本研究以南沙群岛美济礁的生物礁钻孔(南科1井)为研究对象,开展系统的元素地球化学分析。结果显示,钻孔的碳氧同位素具有明显的正相关性,水溶性元素(Sr、Li)含量与矿物组成呈现同步变化,指示以上元素受到了成岩作用的改造,因此难以准确反映原始的古海水信息。相比之下,水不溶性元素(Zr、Hf、稀土元素)含量与δ18O变化的相关性较差,指示以上元素未受到成岩作用的显著改造,能够反映陆源输入变化。在约23~17 Ma阶段,Zr、Hf和稀土元素含量较低,约17 Ma以来明显增加。通过与南海地区已有的古环境记录对比,我们发现,约17 Ma之后陆源物质的增加主要受控于区域范围内的河流输入总量,而并非是单一流域(如湄公河、珠江、红河)造成的影响。此外,黄土高原地区的粉尘通量对于海水性质的影响较小。

       

      Abstract: Coral reefs are one of the most important types of carbonate sediment, preserving vital information about the Earth surface history. Research on coral reefs primarily focuses on paleoecological, sedimentological, and petrographic aspects of reef systems, with comparatively limited investigation of terrigenous input. Extensive reef carbonates have developed in the South China Sea (SCS) since the Miocene, exhibiting high sensitivity to the ocean environment. In this study, we conducted stable isotopes and element analysis of coral reef (NK-1) samples in the Meiji atoll of the Nansha Islands. Our results reveal that the Sr and Li contents are parallel to the mineralogical composition, δ13C and δ18O values exhibit co-varying trend, collectively indicating that these elements and stable isotopes are altered by the diagenetic processes. The Zr, Hf, and ∑REE+Y values exhibit poor relationships with δ18O values, indicating that they are insensitive to the diagenetic processes. Consequently, these elements can serve as reliable proxies for terrigenous input into the marine environment. Our study reveals that Zr, Hf, and ∑REE+Y contents remained relatively low during ca. 23 to 17 Ma but exhibited a marked increase after ca. 17 Ma. By comparing with existing paleoenvironmental records, we propose that the increased terrigenous input since ~17 Ma likely reflects enhanced sediment delivery from the entire SCS drainage system, rather than being dominated by discrete fluvial sources such as the Mekong, Pearl, or Red Rivers. We further suggest that aeolian contributions from the Chinese Loess Plateau played a negligible role in this sedimentary phenomenon.

       

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