南海北部李春海山多金属结核的成因类型及其物质来源探讨:来自矿物特征、地球化学的分析

    Mineralogical and geochemical constraints on genetic types and material sources of ferromanganese nodules in the Lichun seamount of the northern South China Sea

    • 摘要: 前人对大洋多金属结核进行了比较详尽的研究,然而对边缘海陆坡海山多金属结核的研究仍显薄弱。本文以在南海北部陆坡李春海山采集到的多金属结核为研究对象,综合运用分层XRD矿物学、LA-ICPMS原位主微量元素地球化学和分层同位素地球化学等分析测试方法和研究手段,研究南海北部陆坡李春海山多金属结核的成因及其物质来源。李春海山多金属结核存在4个不同单元层(层1、层2、层3、层4),各单元层的矿物组成有所不同,暗示不同的水动力条件和陆源输入速率。李春海山多金属结核主要由水羟锰矿、石英、斜长石组成,但外部的层3和层4锰相矿物除了水羟锰矿,还分别出现水钠锰矿和钡镁锰矿等代表成岩成因类型结核矿物。主成分分析结果表明,李春海山多金属结核具多期多物源成矿特点,成矿特征主要以铁相矿物形成及锰相矿物生长为主。结核内各分层大多数测点Mn/Fe比值均小于2.5,层3与层4内少数测点Mn/Fe比值大于2.5甚至大于5;结核内测点REY配分模式都出现较强的Ce正异常且大多数与南海海水呈镜像对称,而层3和层4少数测点REY配分模式与沉积物孔隙水REY配分模式相近;其Sr-Nd同位素居于南海海水与沉积物之间且接近南海海水,且Pb同位素表现出台湾岛物源的特征。因此,李春海山多金属结核主要为水成成因,后期生长有少量成岩成因组分的混入,物质主要来源于周围海水,同时也受到台湾岛陆源物质输入的影响。

       

      Abstract: Despite the fact that previous studies have been conducted in great detail on oceanic ferromanganese nodules, research on the ferromanganese nodules located on marginal sea slope seamounts remains relatively insufficient. In this study, the ferromanganese nodule collected from Lichun Seamount on the northern slope of the South China Sea was selected as the research subject. By comprehensively employing analytical techniques such as XRD mineralogy, LA-ICPMS in-situ major and trace element geochemistry, and layered isotope geochemistry, the origin and material source of the ferromanganese nodule in Lichun Seamount, northern South China Sea, were investigated.The results reveal that the ferromanganese nodule in Lichun Seamount exhibits four distinct layers (layer 1, layer 2, layer 3, and layer 4), and the mineral composition of each unit layer varies, implying that it has experienced different hydrodynamic conditions and terrigenous input rates during its formation. This nodule is mainly composed of vernadite, quartz, and plagioclase. However, in addition to vernadite, the manganese-phase minerals in layer 3 and layer 4 also contain birnessite and todorokite, suggesting a diagenetic origin. The results of principal component analysis indicate that the ferromanganese nodules in Lichun Seamount are characterized by multi-stage and multi-source mineralization, with the main mineralization features being the formation of iron-phase minerals and the growth of manganese-phase minerals. The Mn/Fe ratio was less than 2.5 at most of the points in each layer, while at a few points in layer 3 and layer 4, the Mn/Fe ratio was greater than 2.5 or even exceeded 5. The REY partition pattern of the detection points within the nodule displayed a strong positive Ce anomaly, and most of them were mirror-symmetric with the South China Sea seawater. The REY partition pattern of a few detection points in layers 3 and 4 was similar to that of the sediment pore water. The Sr-Nd isotope is located between and close to the South China Sea seawater and sediment, and the Pb isotope exhibits the provenance characteristics of Taiwan Island. Therefore, the ferromanganese nodule in Lichun Seamount is mainly of hydrogenetic origin, with a small amount of diagenetic components incorporated during the later growth stage. The materials mainly originate from the surrounding seawater and are also influenced by the input of terrigenous materials from Taiwan Island.

       

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