东海盆地H地区花港组烃源岩特征

    SOURCE ROCKS IN HUAGANG FORMATION OF H AREA, EAST CHINA SEA SHELF BASIN

    • 摘要: 随着东海盆地H地区油气勘探的发现,花港组烃源岩的勘探潜力也日益受到重视。通过烃源岩岩石热解分析、稳定碳同位素分析、镜质体反射率测定以及干酪根组分分析,对烃源岩特征进行研究。结果表明:氯仿沥青“A”组分中饱和烃和芳烃组分的碳同位素组成特征和碳同位素CV值显示研究区花港组泥岩烃源岩存在海陆相有机质;花港组烃源岩镜质体反射率Ro值为0.76%~1.11%,热解最高峰温主体介于440~465 ℃,已进入烃源岩热演化成熟阶段;泥岩烃源岩干酪根类型指数主体<0,热解氢指数<150 mg/g,花港组烃源岩发育Ⅲ型干酪根;泥岩烃源岩有机碳TOC主体<0.5 %,热解生烃潜量S1+S2主体<1 mg/g,氯仿沥青“A”主体<0.05 %,为差泥岩烃源岩。研究区花港组烃源岩煤岩样品热解生烃潜量S1+S2主体>100 mg/g,氯仿沥青“A”主体>1.5 %,氢指数HI主体>275 mg/g,主体为好煤岩烃源岩。总之,研究区煤岩烃源岩品质优于泥岩烃源岩,泥岩烃源岩发育海陆相有机质,且陆相有机质丰度优于海相有机质。

       

      Abstract: With the discovery of oil and gas in the H area of East China Sea Basin, source rocks in the Huagang Formation have raised great attention from geologists. This paper is specially devoted to the source rocks with the newly acquired data of pyrolysis, carbon stable isotope, vitrinite reflectance and kerogen composition. The characteristics of carbon isotopic composition and CV value of saturated hydrocarbon and aromatics suggest that both marine and continental organic matters coexist in the mudstone source rock of Huagang Formation. The vitrinite reflectance varies from 0.76% to 1.11%, and the maximum pyrolysis temperature changes between 440 ℃ and 465 ℃, suggesting that the source rocks remain in a stage of hydrocarbon generation. The kerogen type index of mudstone source rock is less than 0, the pyrolysis hydrogen index is less than 150 mg/g, and the source rocks of the Huagang Formation are characterized by the kerogen of type Ⅲ. The TOC of mudstone source rock is mostly less than 0.5%, the pyrolysis potential of S1+S2 is less than 1mg/g, and the chloroform asphalt “A” is mostly less than 0.05%, so the mudstone source rocks are poor in quality. Analysis of coal samples from source rock of Huagang Formation show that the values of S1+S2, chloroform asphalt “A” and hydrogen index HI are mostly >100 mg/g, >1.5%, and >275 mg/g respectively, indicating a high quality coal-bearing source rock. In a word, the coal-bearing source rocks are better than mudstone source rocks in quality, and the abundance of continental organic matter is higher than that of marine organic matter.

       

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