西沙群岛白云岩-铁白云岩空间变异的特征:来自地球化学的证据

    SPATIAL DISTRIBUTION OF ANKERITE AND DOLOMITE IN THE XISHA ISLANDS: EVIDENCE FROM GEOCHEMISTRY

    • 摘要: 成礁以来西沙群岛白云岩-铁白云岩大量发育,针对白云岩空间变异及成因演化的讨论具有重要意义。西科1井存在7层白云岩,对7层白云岩进行了划区处理,将7层白云岩层分为浅、中、深3类:<600 m为浅层(层一、层二、层三,合计厚度203 m),600~1 000 m为中层(层四、层五、层六,合计厚度79 m),>1 000 m为深层(层七,厚155 m)。通过对7层白云岩的主微量元素特征、成岩环境与成因模式及浅层、中层、深层白云岩地球化学数据之间的规律与差异的分析认为,西科1井白云岩受陆源物质影响小,高的SiO2可能来自西沙周缘火山地带。西沙地区白云岩成岩环境总的来讲属于氧化环境,但浅、中、深层成岩环境的氧化强度具有差异。西科1井白云岩的古盐度都较高,但层与层之间有着细微差异。西科1井白云岩锶含量总体偏低,受到淡水淋滤作用强烈,形成于古水深较浅的礁相台地环境,相比较而言,浅层受到大气淡水影响最强,中层次之,深层最弱。西沙白云岩成岩过程中受到高盐度海水、大气淡水和回流渗透作用等多种因素的影响。

       

      Abstract: Dolomite and ankerite are widely distributed in the Xisha Islands. So far, seven layers of dolomite have been found in the well Xike 1. The seven layers of dolomite may be grouped into three zones, the shallow, the middle and the deep. The shallow zone is less than 600 meters in depth including the layer 1, layer 2 and layer 3 with a total thickness of 203 m; the middle zone includes the layer 4, layer 5 and layer 6 with a total thickness of 79 meters and occurs in a range of 600~1 000 m in depth; the deep zone includes the layer 7, 155 m in thickness buried underground more than 1000 meters in depth. The geochemical characteristics of major and trace elements of the seven layers of dolomite are studied in this paper, while diagenetic environment and genetic model discussed based on the newly acquired geochemical data combined with previous research results. Dolomite in the well Xike 1 was far beyond the affection of terrigenous materials, high content of SiO2 may come from the volcanic activities surrounding the islands. It is evidenced that the dolomitization in the Xisha area happened in an oxidation diagenetic environment, but the intensity of oxidation is different in the shallow, middle and deep zones. The paleosalinity of sea water was high when the dolomites formed, and there are slight differences between the three zones. The content of strontium in the dolomite of the well Xike 1 is generally low, as it was strongly leached by fresh water in an environment of reef platform with relatively shallow water. Comparatively, the influence of atmospheric fresh water was strongest in the shallow zone, followed by those in the middle and deep zones. The diagenesis of dolomite in the Xisha Islands is influenced by many factors, such as high palaeosalinity seawater, atmospheric fresh water and water reflux infiltration.

       

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